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在现代制药工业的生产过程中，不可避免地要使用大量的化学与生物制剂，这带来的一个结果是在生产的每个步骤都会排放出成分复杂的尾气，以挥发性有机化合物(VOC)居多。如何处理含VOC的尾气，成为企业面临的一大环保难题。国内目前主要采用热氧化法的处理方式，即蓄热式热力焚化炉(英文名为“Regenerative Thermal Oxidizer”，简称为“RTO”)
二、RTO工作原理
把有机废气加热到760摄氏度以上，使废气中的VOC在氧化分解成二氧化碳和水。废气首先通过蓄热体加热到接近热氧化温度，而后进入燃烧室进行热氧化，氧化后的气体温度升高，有机物基本上转化成二氧化碳和水。净化后的气体，经过另一蓄热体，温度下降，达到排放标准后排放。不同蓄热体之间通过切换阀，随时间进行转换，分别进行吸热和放热。氧化产生的高温气体流经特制的陶瓷蓄热体，使陶瓷体升温而“蓄热”，此“蓄热”用于预热后续进入的有机废气，从而节省废气升温的燃料消耗。陶瓷蓄热体应分成两个(含两个)以上的区或室，每个蓄热室依次经历蓄热-放热-清扫等程序，周而复始，连续工作。蓄热室“放热”后应立即通过反吹风机对该蓄热室进行清扫(以保证VOC去除率在95%以上)，只有待清扫完成后才能进入“蓄热”程序。RTO设备的工作流程见下图：
三、控制要求和方法
3.1. 燃烧器控制
氧化室安装一个带比例调节的天然气燃烧器。燃烧器的供热量是用氧化室温度，经过PID调节器自动调节，当燃烧器运行时，燃烧器PID的SP外给定值(TE05_AM)等于SP外给定值+升温速率设定值/120。按照升温曲线进行升温。否则，SP外给定值等于氧化室温度。如果SP外给定值超过TE05_S10(氧化室温度--理想控制温度设定)，那么TE05_S10直接赋值给TE05_AM(SP外给定值)，进行温度限制。此外，燃烧系统还带有熄火保护、超温报警和超温自动停燃烧器等功能。
3.2.进气、出气、清扫流程的切换
该设备有三个蓄热室，一个公共氧化室，有机废气通过鼓风机送入蓄热室1，吸热后进入氧化室，蓄热室1因放热而降温，燃烧升温后的气体进入蓄热室2，通过热交换把热量蓄存在蓄热室2的陶瓷蓄热体中，处理后的气体经后续处理合格后烟囱排空。同时蓄热室3空间中残留未处理的VOC废气被反吹风机吹回氧化室焚化处理。经过一段时间(约2分钟(可设定))后，气流改变方向从蓄热室2进入氧化室，通过蓄热室2吸收热量升温后，在氧化室内高温焚化，最后经蓄热室3热交换后排放，同时蓄热室1处于清扫状态，经过一段时间(约2分钟(可设定))后，气流再次改变方向，不断的交替循环，保证氧化室温度在800℃以上，以此保证高的去除率和换热效率。程序如下图：
OMRON C500-NC211 USPP C500NC211
ORIENTAL MOTOR UDX5128 NSFP UDX5128
Siemens 6ES5 456-4UA11 6ES54564UA11
Siemens 6ES5-928-3UB11 USPP 6ES59283UB11
SIEMENS 6ES5-441-8MA11 6ES54418MA11 INPUT MODULE 5 NOS WITH BASE
Siemens 6ES5 440-8MA21/6ES5440-8MA21 OUTPUT MODULE XLNT
Siemens 6ES7 131-4BD00-0AA0 with 6ES7 193-4CA20-0AA0
Siemens 6SE7090-0XX84-0AB0 Masterdrives CUVC Board ~VERSION~, REAL PHOTOS
Siemens 6ES7 332-5HD01-0AB0 -- 6ES73325HD010AB0
Siemens U-20T
MODICON AS-J810-000 INTERFACE MODULE ASJ810000
WS-X4712-SFPE Cisco Catalyst 4500 E-Series 12Pt.-10GBE SFP MODULE
SIEMENS 6ES7 413-1XG02-0AB0 6ES74131XG020AB0
Siemens Rectifier Module GR40
Reliance 0-57200
Schneider Modicon MARILYN MONROE - Marilyn AS úLTIMAS SESSES Michel - BOOK / PORT.
Schneider Modicon AS-B247-001 USPP ASB247001
Schneider Modicon AS-P933-001 NSFP ASP933001
Schneider Modicon AS-B829-116 5V TTL FAST INPUT
Schneider Modicon AS-B801-000 ASB801000 Spare Slot Filler LNC
MODICON MM-PMC2-300 OPERATOR INTERFACE PANEL
Siemens Simatic 505-4232A 110VAC Input Module
SIEMENS 6ES5-315-8MA11 NSPP 6ES53158MA11
SIEMENS S5 PLC 6ES5-440-8MA21 OUTPUT MODULE PARTS FOR 3 MONTH WARRANTY
SIEMENS 6DD1-684-0AB0/6DD1684-0AB0 RIBBON CABLE APPROX. 2 METERS NNB
SIEMENS SINUMERIK 820 6EW1861-3AB POWER SUPPLY 6EW18613AB
SIEMENS 6SN1-112-1AB00-0BA0 NSFP 6SN11121AB000BA0
SIEMENS SimoDrive 650 I/O 6SC6500-OBB01 _6SC 6500-0BB01
SIEMENS 6FC9348-7DM Cable Connector - Surplus
Advantech MIC-3351
ALLEN-BRADLEY 1771-ODC/B ISOLATED AC OUTPUT MODULE
ABB ACS601-0060-4-000B1200801
Adaptive Alpha Vision PC Stadium Sign AVPC320112T3 _ AVPC32O112T3
6ES7478-2DA10-0AC0 Brand , Factory Sealed,
9004V012X5 SQUARE D 9004 V012X5
SQUARE D NF1000G3N2 NSFP NF1000G3N2
CONTROL TECHNIQUES FX-6120 USPP FX6120
BENTLY NEVADA 3300-16-02-01-01-01-02-00 USPP 3300160201010102
MTS SYSTEMS CO 469876-01 USPP 46987601
MAYR 4105418 USPP 4105418
FANUC A06B-0502-B002 USPP A06B0502B002
Siemens 6ES5 155-3UA12 6ES51553UA12
Siemens 6ES5-465-4UA13 USPP 6ES54654UA13
SIEMENS 6ES5 090-8MA01 6ES5 090-8MA01S5-90U Controller 60 DAYS WARRANTY
SIEMENS S5 6ES5-464-8ME11 ANALOG INPUT
Siemens 2pcs S5 6ES5 316-8MA12 Interface Module
Siemens 6ES7332-7ND02-0AB0 6ES7 332-7ND02-0AB0 NIB
Siemens SITOR Fuse 3NE3336 3NE3 336
Siemens 6ES5373-0AA41
Inc VAT tested
YOSHIMURA FOR KAWASAKI KFX450R 08-10
Siemens 6ES5464-8MC11 6ES5 464-8MC11
SIEMENS MP277-10 6AV6 643-0CD01-1AX1 Touch Glass
Omron S82G-1524
Schneider Modicon AS-BADU-206/ASBADU206 Analog Input NICEOFFERS ACCEPTED
Schneider Modicon AS-506P-F32 NSPP AS506PF32
Schneider Modicon AS-J892-101 INTERFACE MODULE S908 RIO INTERFACE ASCII
Schneider Modicon AS-5318-000 NSPP AS5318000
Schneider Modicon ICC/Cyberline 100-0037 Control Card AS-IS
Schneider Modicon Automation AS-B805-016 16 PLC Module
SIEMENS/TEXAS INSTRUMENTS 505-6108 INPUT MODULE XLNT
Schneider TWIDO TWDLMDA40DUK
Siemens Sinumerik Machine Control Panel 3T 548 025 9004
SIEMENS 500-5056 DIGITAL OUTPUT MODULE 5005056
SIEMENS SINUMERIK 810 I/O BOARD 6FX 1126-5AA
Comms Option Module Control Techniques Communications Module E/W: 267743
SIEMENS SIMODRIVE 6SN1146-1AB00-0BA1SINUMETIK 840D NCU-BOX 6FC5247-0AA00-0AA2#4
SIEMENS SIMODRIVE 6SN1145-1AA01-0AA1SINUMETIK 840D NCU-BOX 6FC52476FC5357 6SN
Advantech Input Module ADAM-3011 NIB
ALLEN-BRADLEY 6181-ACAAZZZZZ Operator Interface Panel
ABB 3HAB2207-1/3 DRIVE BOARD 3HAB22071
ACCURAY 083886-001 USPP 083886001
A06B-6117-H104 FANUC SERVO AMP MODULE
809A08E ALLEN BRADLEY 809 A08E
SIEMENS 6ES5-581-1EA11 USPP 6ES55811EA11
ASEA BROWN BOVERI 52700141 USPP 52700141
ALLEN BRADLEY 6182H-12TRH4A USPP 6182H12TRH4A
LENZE EVS9327-ES USPP EVS9327ES
HARMONIC DRIVE 479543-1 NSFP 4795431
ALLEN BRADLEY 1336-B003-EAD-FA2-L3-S1 NSPP 1336B003EADFA2L3
RELIANCE ELECTRIC 0-51839-11 NSPP 05183911
Siemens 6ES5-350-3KA21 NSPP 6ES53503KA21
SIEMENS 6ES5 441-7LA13 6ES54417LA13
SIEMENS Serial Interface Module 6ES5 521-8MA22 SURPLUS No Paperwork
Siemens MODULES5 6ES5 422-8MA11 6ES54228MA11
Siemens 6ES7 235-0KD22-0XA0 6ES7235-0KD22-0XA0 FreeShip
SIEMENS OP7 6AV3607-1JC30-0AX1 Membrane Keypad
PWR-RPS2300 CISCO REDUNDANT POWER SYSTEM 2300 AND BLOWER
GPNP NT512 NT384 ISDN Interface Module
Trillium Panther II 90-0471 PII SMDR Interface Module
SIEMENS 64kB MMC 6ES7 953-8LF20-0AA0 in Box
Siemens GSM TC35 SIM CARD
Modicon PP-0105-000
Schneider Modicon GOULD AS-B557-000 INPUT MODULE 5V TTL
Schneider Modicon ASH827103 800 Series Rack AS-H827-103
Schneider Modicon AS-D285-036 NSFP ASD285036
Schneider Modicon AS-P840-000
Schneider Modicon ADU205/AS-BADR-205
Schneider Modicon Modem Assembly AS-J378-000 Old Stock
Schneider Telemecanique XBTZ9731 Cable
Schneider Modicon TM2AMI8HT in Box
Price includes VAT-Good conditiongood working order
SIEMENS 6ES5 450-8MD11 DIGITAL OUTPUT MODULE
SIEMENS 6FC5235-0AA05-0AA1 SINUMERIK 3.5 FLOPPY
HONEYWELL 620-0042 CIM 6200042 COMMUNICATION INTERFACE MODULE CARD
SIEMENS SIMODRIVE 6SN1145-1BA02-OCAO
SIEMENS Sinumerik 805 6FC4100-1AA00-Z Free Ship
SIEMENS MOORE 162566-61-1 16256-61-1 BDM TERMINATE MODULE TERMINATION 22594
Allen-Bradley PanelView 1400e 2711E-T14C6 Ser C Rev A
555DXRE Electric Conduit Bender w/ 12580 Shoe Group 1/2" a�“ 2" Rigid/EMT
ABB TRANSFORMER 3HAB-7167-1 475-600V 3 PH 3HAB7167-1 475-600V
A06B-0153-B084#7076 FANUC SERVO MOTORS REMANUFACTURED
7300AVPT1 ALLEN BRADLEY POWER SUPPLY REMANUFACTURED
RELIANCE ELECTRIC 3RA2008 USPP 3RA2008
ALLEN BRADLEY 1785-L60L/E USPP 1785L60LE
ALLEN BRADLEY 150-A35NCD USPP 150A35NCD
GENERAL ELECTRIC IS200VCRCH1ABA NSPP IS200VCRCH1ABA
TOTAL CONTROL PRODUCTS QPI-3D200-C2P USPP QPI3D200C2P
SYMAX 8030-ROM-122 NSFP 8030ROM122
FOXBORO A7000DV USPP A7000DV
Siemens 6ES5-102-8MA02 NSFP 6ES51028MA02
SIEMENS 6ES5 373-0AA81 6ES53730AA81
SIEMENS 6ES5-941-7UA11 USPP 6ES59417UA11
Siemens 6ES5 737-1CB00 USPP 6ES57371CB00
Siemens 6ES5 095-8MC03
Siemens LOGO! DM8 12/24R 6ED1 055-1MB00-0BA1
Rexroth Indracontrol L40 CML40.1-NP-220-NA-NNNN-NW
Texas Instruments 2493295-0002
SPEEDTRONIC MODULE DS3820 PIMB INTERFACE IN BOX
VWIC-1MFT-G703 CISCO 1-PORT RJ-48 MULTIFLEX TRUNK G.703
Siemens C7-634 6ES7634-1DF02-0AE3 Membrane Keypad
Modicon AS-T584-204
Schneider Modicon AUTOMATION DEP216/AS-BDEP-216/ 042244630
Schneider Modicon TSX Compact DAP 220/AS-BDAP-220 DAP220ASBDAP220
Schneider Modicon AS-B885-111 MODULE MOTION ASB885111
Schneider Modicon AS-B575-201
Schneider Modicon PLC AS-P890-000 AS-IS PARTS OR REPAIR
Schneider Modicon AS-P965-000 | 12 mo. warranty | Free UK/EU Shipping | Price Inc UK VAT
Schneider Automation / Modicon PanelMate Plus MM-PM22400C WARRANTY
Sharp JW-34N INPUT MODULE 32POINTS 12/24 VDC
RELIANCE ELECTRIC 0-49005-5 LINEAR VOLTAGE TIME UNIT
SIEMENS 6ES7-131-4BD00-0AA0/6ES7131-4BD00-0AA0 OUTPUT MODULE LOT OF 2 XLNT
SIEMENS 6DD1642-0BC0Analog Output Module SDYND EA12
OMRON 3G2A9-AL004-PE COMMUNICATIONS MODULE
SIEMENS SIMODRIVE 611 6SN1111-0AA01-1BA1
SIEMENS Sinumerik Operator Panel 6FC5203-0AF26-0AA0-Z 6FC5203 0AF26 0AA0 Z
SIEMENS Jacobs Chuck 0080725FC JCCAT40xER25-6-FC Tool Holder
ALLENBRADLEY1771OBOUTPUTMODULE8POINT12-24VDC
Allen Bradley SLC-500 Input Module 16-Point 1746-IA16
ABB PFV1-101 POWER SUPPLY PFV1101 YM110001SP
york 031-01065-002 control board rev h
/REFURB REXROTH INDRAMAT HDS03.2-W075N-HS12-01-FW
MODICON AS-506P-F32 USPP AS506PF32
ALLEN BRADLEY 1394-SJT10-C-RL USPP 1394SJT10CRL
GETTYS 110-235 NSFP 110235
GE FANUC IC3600AVIA1D USPP IC3600AVIA1D
SIEMENS 6SC9121-5CD15 USPP 6SC91215CD15
SIEMENS 3VL31252GB300AA0 NSFP 3VL31252GB300AA0
ALLEN BRADLEY 1305-BA09A-DE USPP 1305BA09ADE
Siemens 6ES5 921-3UA12 -- 6ES59213UA12
Siemens S5 6ES5 928-3UB11 6ES59283UB11 Processor
SIEMENS 6ES5-470-8MB11 USPP 6ES54708MB11
Siemens 6ES5 430-7LA11S5 Input Module 17789
Siemens S5 Sub Rack CR1 6ES5 700-1LA12 E Stand 01
Siemens DCS Module 6DS1327-8AA in Box, Seal opened,
SEALEDASA5540-AIP20-K9 CISCO 5540 W/AIP-SSM-20 SW HA 4GE1FE 3DES/AES
Square D 8501 XC1
Siemens 6ES5301-3AB13 Interface Module 60 DAY WARRANTY FREE
WE SHIP SAME CISCO WS-C3750V2-24PS-E SWICTH 1 YR 3750V2-24P
Siemens 6GK7 443-1EX11-0XE0 6GK74431EX110XE0 NIB
Siemens TP177B 6AV6642-0BA01-1AX0 Touchscreen Glass
Schneider Modicon / TSX Compact AS-P120-250 AC Power Supply - ASP120250
Schneider Modicon ASBADU206 TESTED and GUARANTEED Compact Analog Input AS-BADU-206
Schneider Modicon AS-B873-001 INPUT MODULE ANALOG 4-20MA 4POINT
Schneider Modicon AS-B875-111
Schneider Modicon AS-C921-000
Schneider Modicon AS-BBKF-201 Interbus-S Master Module
Schneider/Modicon MM-PM21400C PanelMate Plus 2000C
SIEMENS 6ES7 321-1BH50-0AA0 DIGITAL INPUT MODULE GOOD TAKEOUT
Sans Digital HA-ARC-ARC1223X 2-Port Mini-SAS 6G SAS/SATA PCIe 2.0 x8 Controller
SIEMENS EA-12 ANALOG OUTPUT MODULE 6DD1642-0BC0
SIEMENS SINUMERIK 810 6FX1128-1BA00 WITH MODULES TESTED WARRANTY
Siemens 505-7354 Communication Module Peer Link
SIEMENS 6SN1145-1BA01-0DA1 | 12mo warranty | Free EU Shipping | Inc UK VAT
SIEMENS 6SN1112-1AB00-1AA0 6SN1 112-1AB00-1AA0 SIMODRIVE 611 Capacitor Module
SIEMENS 6FC5-114-0AA02-0AA0 USPP 6FC51140AA020AA0
AllenBradleyMountingClipKit4-PiecePanelview600Cat77135-166-55
ALLEN BRADLEY X-232820 NSFP X232820
ABB DSQC 115
Adimec MX12P Progressive scan Camera (ISS1.0) w/ Nikon AF Nikkor 1:1.8 85MM Lens
(A0) 1 Brand Rosemount 3051S Transmitter SEE PICS (A0)
INDRAMAT TVD1.3-08-03 USPP TVD130803
YAMATAKE 82114805-501 USPP 82114805501
FANUC A20B-0002-0942 NSPP A20B00020942
ENDRESS & HAUSER 33FT50-AD1AA11A21A NSPP 33FT50AD1AA11A21
RELIANCE ELECTRIC 86495-1R USPP 864951R
OMRON CVM1-CPU21-EV2 USPP CVM1CPU21EV2
PACIFIC SCIENTIFIC R46GENA-TS-NS-VS-00 NSFP R46GENATSNSVS00
Siemens 6ES5 451-4UA13 -FS- 6ES54514UA13
Siemens 6ES5-922-3UA11 NSFP 6ES59223UA11
SIEMENS 6ES5-420-3BA11 USPP 6ES54203BA11
Siemens 6ES5 441-8MA11 Digital Output Module 26675
Siemens S5 6ES5 421-8MA12 INPUT MODULE 2 BASE
Siemens 6SE7090-0XX84-6FF5
Siemens 6ES7 331-7KF02-0AB0 -- 6ES73317KF020AB0
Spectrum Controls 8000 SCP-204
Nady UIM-2X USB Interface Module with Phantom Power
WS-X45-SUP6L-E Cisco Supervisor Engine 6L-E Control processor
SIEMENS 6ES7 621-1AD01-0AE3 C7-621 99%
Siemens RWX62.734/509 Controller
Reliance 11C409S
Schneider Modicon Helen .. Right As Rain
Schneider Modicon AS-B260-010 USPP ASB260010
Schneider Modicon AS-S202-020 USPP ASS202020
Schneider Modicon AS-B840-108 800 I/O REED RELAY MODULE
Schneider Modicon AS-B804-016 ASB804016 16 Point 120 VAC Output
MODICON MM-PM10-200 PANELMATE PLUS MONITOR
SIEMENS SIGA-CC1-LG MODULE SINGLE INPUT SIGNAL-
Siemens 6ES5 523-3UA11 6ES55233UA11
SIEMENS S5 6ES5 458-7LA11 Relay Output Module
SIEMENS 6DD3-470-0AD0/6DD3470-0AD0 BOARD XLNT
SIEMENS SINUMERIK 840D/DE NCU 572.4 6FC5357-0BB23-0AE0 NIB
SIEMENS 6SN1113-1AB01-0BA1 Pulsed Resistor Simodrive -
SIEMENS Simodrive 611 E/R 6SN1146-1BB00-0DA1 NIB
